Safety of 2,4-Dichlorobenzoic acid. Recently I am researching about STRUCTURAL-CHARACTERIZATION; OXIDATION; OXO; RUTHENIUM, Saw an article supported by the Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21372007]; Natural Science Foundation of Anhui ProvinceNatural Science Foundation of Anhui Province [2008085 MB58]. Published in ELSEVIER SCIENCE SA in LAUSANNE ,Authors: Qian, BF; Wang, JL; Jia, AQ; Shi, HT; Zhang, QF. The CAS is 50-84-0. Through research, I have a further understanding and discovery of 2,4-Dichlorobenzoic acid
Treatment of [(Me3tacn)RuCl3 center dot H2O] (Me3tacn = 1,4,7-trimethyl-1,4,7-tri-azacyclononane) with substituted benzoic acid or phenylacetic acid, in water in the presence of potassium hexafluorophosphate gave a series of cationic dinuclear Ru(III)-Ru(III) (mu-oxo)bis(mu-carboxylato) complexes [(Me3tacn)2Ru2(mu-O)(mu-OOCR)2](PF6)2 (R = Ph, 1; -py, 2; -C6H4-2-Cl, 3; -C6H3-2,4-Cl2, 4; -CH2C6H4-2-CH3, 5; -CH2C6H4-4-CH3, 6; -CH2C6H4-4-OCH3, 7; -CH2C6H4-4-Cl, 8). All complexes are well characterized by infrared, UV/Vis and mass spectroscopies, and their electrochemical properties were also investigated. The molecular structures of 1, 2 center dot 2C3H6O, 5 center dot 2C3H6O, 7 and 8 have been also established by single-crystal X-ray diffraction. The photocatalytic properties for H2 evolution by water splitting of complexes 1, 2, 3, 5, and 7 were also investigated in the paper.
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Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics