Recently I am researching about CHEMISTRY; AZIDE; REACTIVITY; 1,2,3-TRIAZOLES; CYCLOADDITIONS; CATALYSTS; BASE, Saw an article supported by the Higher Education Commission (HEC) of PakistanHigher Education Commission of Pakistan. Published in MAIK NAUKA/INTERPERIODICA/SPRINGER in NEW YORK ,Authors: Jabeen, S; Khera, RA; Iqbal, J; Asgher, M. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene. Application In Synthesis of 1-Chloro-2-methylbenzene
A series of new triazole ligands has been synthesized via copper-catalyzed cycloaddition reaction of readily available azides and alkynes. The synthesized compounds were characterized by FTIR, H-1 and C-13 NMR, and high-resolution mass spectra. The ligands provided excellent yields (up to 92%) in the palladium-catalyzed Suzuki-Miyaura cross coupling of unactivated aryl chlorides with phenylboronic acid. 1-Benzyl-4-(2,6-dimethoxyphenyl)-lH-1,2,3-triazole was found to be the most effective ligand due to the presence of electron-donating 2,6-dimethoxyphenyl substituent, which made it possible to develop a highly active ligand-catalyst system for the Suzuki reaction of aryl chlorides.
Application In Synthesis of 1-Chloro-2-methylbenzene. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Jabeen, S; Khera, RA; Iqbal, J; Asgher, M or concate me.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
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