An article Iron-Catalyzed Regioselective alpha-C-H Alkylation of N-Methylanilines: Cross-Dehydrogenative Coupling between Unactivated C(sp(3))-H and C(sp(3))-H Bonds via a Radical Process WOS:000471212000028 published article about PRIMARY AMINES; INTERMOLECULAR HYDROAMINOALKYLATION; REDUCTIVE AMINATION; SELECTIVE SYNTHESIS; ONE-POT; EFFICIENT; NITRILES; ALKENES; N-(CYCLOHEXYLMETHYL)-N-ALKYLAMINES; TETRACARBONYLHYDRIDOFERRATE in [Li, Ze-Lin; Sun, Kang-Kang; Wu, Peng-Yu; Cai, Chun] Nanjing Univ Sci & Technol, Chem Engn Coll, Nanjing 210094, Jiangsu, Peoples R China; [Cai, Chun] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Lu, Shanghai 20032, Peoples R China in 2019.0, Cited 56.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8. HPLC of Formula: C7H7Cl
The iron-catalyzed alpha-C-H alkylation of N-methylanilines without any directing group by cross-dehydrogenative coupling between unactivated C(sp(3))-H and C(sp(3))-H bonds has been established for the first time, which provides a good complement to C(sp(3))-H activation reactions and expands the field of Fe-catalyzed C-H functionalizations. Many different C(sp(3))-H bonds in cyclic alkanes, cyclic ethers, and toluene derivatives can be used as coupling partners. Mechanistic investigations including the radical reaction process, the main role of various reagents, and the kinetic isotope effect experiment were also described.
HPLC of Formula: C7H7Cl. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Li, ZL; Sun, KK; Wu, PY; Cai, C or concate me.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics