Category: chlorides-buliding-blocks. I found the field of Chemistry very interesting. Saw the article C(sp(3))-H activation-enabled cross-coupling of two aryl halides: an approach to 9,10-dihydrophenanthrenes published in 2020, Reprint Addresses Zhang, YH (corresponding author), Tongji Univ, Sch Chem Sci & Engn, Shanghai Key Lab Chem Assessment & Sustainabil, 1239 Siping Rd, Shanghai 200092, Peoples R China.. The CAS is 50-84-0. Through research, I have a further understanding and discovery of 2,4-Dichlorobenzoic acid.
A palladium-catalyzed cross-coupling reaction of aryl halides with 2-chlorobenzoic acids has been developed. The reaction forms C(sp(3)), C(sp(2))-palladacycles through C(sp(3))-H activation. The palladacycles react with 2-chlorobenzoic acids through two successive C-C cross-couplings, and two C-C bonds are formed with high chemoselectivity. The reaction provides an innovative method for the synthesis of 9,10-dihydrophenanthrenes.
About 2,4-Dichlorobenzoic acid, If you have any questions, you can contact Gu, YC; Sun, XL; Wan, B; Lu, ZE; Zhang, YH or concate me.. Category: chlorides-buliding-blocks
Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics