An article Ligand Control of Palladium-Catalyzed Site-Selective alpha- and gamma-Arylation of alpha,beta-Unsaturated Ketones with (Hetero)aryl Halides WOS:000586299200001 published article about REDUCTIVE ELIMINATION; CARBONYL-COMPOUNDS; ARYL HALIDES; DESIGN; POSITION; ACETONE; BONDS in [Yuen, On Ying; So, Chau Ming] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hung Hom, Hong Kong, Peoples R China; [Yuen, On Ying; So, Chau Ming] Hong Kong Polytech Univ, State Key Lab Chem Biol & Drug Discovery, Hung Hom, Kowloon, Hong Kong, Peoples R China; [So, Chau Ming] Hong Kong Polytech Univ, Shenzhen Res Inst, Shenzhen, Peoples R China in 2020.0, Cited 45.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8. Computed Properties of C7H7Cl
This study describes the first palladium-catalyzed, site-selective alpha- and gamma-arylation of alpha,beta-unsaturated ketones with (hetero)aryl halides. A wide range of hetero(aryl)halides coupled with alpha,beta-unsaturated ketones, and transformation into the arylated products proceeded with excellent to good yields. The site selectivity of the reaction is switchable by simply changing the phosphine ligand to access either alpha-arylated or gamma-arylated products in good to excellent yields by using a low catalyst loading, and the method demonstrates good functional-group compatibility.
About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Yuen, OY; So, CM or concate me.. Computed Properties of C7H7Cl
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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