3386-33-2, Adding a certain compound to certain chemical reactions, such as: 3386-33-2, name is 1-Chlorooctadecane, belongs to chlorides-buliding-blocks compound, can increase the reaction rate and produce products with better performance than those obtained under traditional synthetic methods. Here is a downstream synthesis route of the compound 3386-33-2.
Diallylphenol (3.48 gm, 0.02 mol) was diluted in dimethyl sulfoxide (50 ml) and sodium hydroxide (0.8 gm, 0.02 mol) added to the solution followed by 1-chlorooctadecane (5.78 gm, 0.02 mol) and heated at 80 C. for 2 hrs. After cooling and diluting with water, the reaction mixture was extracted with hexane, dried over MgSO4 filtered and evaporated to give the desired product. MS m/z 426. (M+ calcd for C30H50O=426). H NMR (300 MHz, CDCl3) d 0.80 (t ,3, CH3), 1.25 (s, 32, CH2).1.75-1.80 (m, 2, CH2), 3.30-3.40 (d, 4, CH2), 3.70-3.80 (t, 2, OCH2), 5.05-5.21(m, 2, CH2 vinyl), 5.95-6.10 (m, 2,CH2 vinyl), 7.00-7.20(m, 3, aromatic). Oxidation with MCPBA as described in Example 1 gave 2,6-di(epoxypropyl)phenyl octadecyl ether. MS m/z 458 (M+ calcd for C30H50O3=458). H NMR (300 MHz, CDCl3) d 0.80 (t, 3, CH3), 1.25 (s, 30, CH2), 2.60-2.70 (m, 2, CH2 epoxypropyl), 2.75-3.10 (m, 6, CH2 epoxypropyl), 3.20-3.30 (m, 2, epoxypropyl CH), 3.55-3.75 (t, 2, CH2), 7.10-7.25 (m, 1, aromatic), 7.40-7.60 (m, 2, aromatic).
In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles, 1-Chlorooctadecane, other downstream synthetic routes, hurry up and to see.
Reference:
Patent; Pews, R. Garth; US2005/90673; (2005); A1;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics